Data from a special run of the LHC using dedicated beam optics at 7 TeV have been analysed to measure the total cross-section of proton-proton collisions in ATLAS. Using the Absolute Luminosity For ATLAS (ALFA), a Roman Pot sub-detector located 240 metres from the collision point, ATLAS has determined the cross-section with unprecedented precision to be σtot (pp → X) = 95.4 ± 1.4 millibarn.